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- W2952156737 abstract "ortho-Lithiation of N,N-diisopropyl-P,P-diphenylphosphinothioic amide using n-BuLi in the presence of TMEDA in diethyl ether followed by electrophilic trapping is described as an efficient method for the synthesis of ortho-functionalised derivatives in high yields. The structural modification of the phosphinothioic amide includes C–X (X = P, S, Si, Sn, I) and C–C bond forming reactions with a large variety of electrophiles. Additional applications based on functional group transformations are also reported. They include imine formation, desulfurization and Suzuki cross-coupling reactions on selected compounds." @default.
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- W2952156737 date "2013-01-08" @default.
- W2952156737 modified "2023-10-16" @default.
- W2952156737 title "ChemInform Abstract: Transformations of Diphenylphosphinothioic Acid Tertiary Amides Mediated by Directed ortho Metallation." @default.
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- W2952156737 doi "https://doi.org/10.1002/chin.201302165" @default.
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