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• W2952158308 endingPage "84" @default.
• W2952158308 startingPage "54" @default.
• W2952158308 abstract "The accurate selection of a ligand for a metal-catalyzed homogeneous reaction can be as decisive as the selection of the metal. Incorporating a carborane cage as a backbone to produce new phosphines often leads to remarkable properties, which are not accessible employing conventional organic entities. The synergy effects between the o-carborane cluster and the P atom in these closo- and nido-carboranylphosphines is observed from two points of view: the cluster and the P atom. The P atoms in the closo-carboranylmonophosphines grant to the cluster a unique plasticity on the CclusterCcluster distance. The cooperation between the carboranyl moiety and the P atom may result in mono-, di- and tridendicity according to the necessities of the metal, not an ever-available property for organic phosphines." @default.
• W2952158308 created "2019-06-27" @default.
• W2952158308 creator A5031568797 @default.
• W2952158308 creator A5035172341 @default.
• W2952158308 creator A5084168197 @default.
• W2952158308 date "2014-06-01" @default.
• W2952158308 modified "2023-10-18" @default.
• W2952158308 title "Metal promoted charge and hapticities of phosphines: The uniqueness of carboranylphosphines" @default.
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