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- W2952158696 abstract "A new regiospecific route to 2,4-disubstituted thiophenes has been developed through Simmon–Smith reaction on β-methylthio-α,β-unsaturated ketones. Extension of the reaction to β-ethyl/benzylthio-α,β-unsaturated ketones also gave the corresponding 2,4-disubstituted thiophenes in a regiospecific manner. A probable mechanism involving a carbenoid methylene insertion to divalent sulfur followed by intramolecular aldol condensation has been suggested. Download : Download full-size image" @default.
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- W2952158696 date "2013-01-01" @default.
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- W2952158696 title "Attempted Simmon–Smith reaction on β-alkylthio-α,β-unsaturated ketones: a regiospecific synthesis of 2,4-disubstituted thiophenes" @default.
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- W2952158696 doi "https://doi.org/10.1016/j.tetlet.2012.10.110" @default.
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