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- W2952165082 abstract "Product studies of Cl atom initiated oxidation of ClCH2CHO and Br atom initiated oxidation of BrCH2CHO were conducted by FTIR spectroscopy at 297 ± 2 K in 700 Torr of O2/N2 diluent, using reactant partial pressures in both the torr and millitorr ranges. The halogen atoms initiate reaction via hydrogen abstraction from the aldehydic group (CHO), producing haloacetyl radicals, XCH2CO, where X = Cl or Br. In 700 Torr of air, the XCH2CO radicals may react via three channels: (i) O2-addition, XCH2CO + O2 → XCH2C(O)O2; (ii) unimolecular dissociation by CC bond cleavage, XCH2CO (+M) → XCH2 + CO (+M); and (iii) unimolecular dissociation by CX bond cleavage, XCH2CO (+M) → X + CH2CO (+M). All three channels were observed for BrCH2CO radicals, enabling estimation of the branching ratios, but ClCH2CO reacts only by O2-addition. Subsequent reactions of XCH2C(O)O2 radicals lead to XCH2O radical and CO2 formation. The ClCH2O radical reacts with O2 to produce CHClO and HO2, while the BrCH2O radical mainly eliminates the..." @default.
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- W2952165082 date "1996-04-18" @default.
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- W2952165082 title "FTIR Spectroscopic Studies of the Mechanisms of the Halogen Atom Initiated Oxidation of Haloacetaldehydes" @default.
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- W2952165082 doi "https://doi.org/10.1021/jp953103q" @default.
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