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- W2952176985 abstract "Two catalytic cycles operate in the osmium-catalyzed olefin dihydroxylation and aminohydroxylation. Slow hydrolysis of the Os(VI) monoglycolate (or monoazaglycolate in aminohydroxylation) intermediate often results in the addition of another molecule of olefin thereby shunting the catalysis into the second catalytic cycle. As a result, both enantio- and chemoselectivity are reduced. A series of new chelating ligands were devised, which force the catalysis into the second cycle while maintaining enantiocontrol in the olefin addition step. Excellent catalytic turnover and moderate to good enantioselectivity were achieved." @default.
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- W2952176985 date "2006-11-07" @default.
- W2952176985 modified "2023-09-24" @default.
- W2952176985 title "Osmium-Catalyzed Olefin Dihydroxylation and Aminohydroxylation in the Second Catalytic Cycle." @default.
- W2952176985 cites W2110106556 @default.
- W2952176985 doi "https://doi.org/10.1002/chin.200645025" @default.
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