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- W2952181565 abstract "Dark red and dark brown crystals of Yb4Sb2S11.25 and Tm8Sb4Se11.68, respectively, were obtained from the reaction of the elements in Sb2Q3 (Q=S, Se) fluxes. Both non-stoichiometric compounds are orthorhombic and crystallize in the same space group Pnnm, with two formula units per unit cell (a=12.446(2), b=5.341(1), c=12.058(2) for sulfide and a=13.126(2), b=5.623(1), c=12.499(2) for the selenide). Their crystal structures are dominated by lanthanide-chalcogenide polyhedra (CN=7 and 8), which share corners, edges, triangular- and square-faces to form a three-dimensional framework embedding antinomy cations. The latter are coordinated by three sulfide anions with 5(1+2+2) secondary contacts forming basically infinite chains running along [0 1 0]. The chalcogens in both compounds form chalcogenide Q2− and dichalcogenide (Q2)2− anionic units. The optical analysis made on those compounds shows that both are semiconductors with band gap of 1.71 and 1.22 eV for Yb4Sb2S11.25 and Tm4Sb2Se11.75, respectively." @default.
- W2952181565 created "2019-06-27" @default.
- W2952181565 creator A5051810231 @default.
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- W2952181565 date "2012-03-01" @default.
- W2952181565 modified "2023-09-25" @default.
- W2952181565 title "Two new ternary lanthanide antimony chalcogenides: Yb4Sb2S11.25 and Tm4Sb2Se11.68 containing chalcogenide Q2− and dichalcogenide (Q2)2− anions" @default.
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- W2952181565 doi "https://doi.org/10.1016/j.jssc.2012.01.020" @default.
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