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- W2952185280 abstract "Abstract Based on our earlier observation that para-halogenated phenoxy triazines self-assemble as hexagonal nanoporous frameworks, this study deals with the inclusion of structurally related guest species in the one-dimensional channels of the title host compounds. A systematic analysis of six isomorphous, X-ray crystal structures (space group P63/m) provides valuable information of wide-ranging implications in host–guest chemistry: (1) construction of a host lattice with weak intermolecular interactions; (2) correlation of guest-size and host–channel area with order/disorder in the host; (3) role of molecular symmetry and multi-point hydrogen bond recognition for ordered guest species; (4) unusual structural behaviour and properties of guests constrained in a narrow channel. Lastly, a ternary adduct crystal shows an intricate hydrogen bonding network in the polar space group R3c with a super-cell of c=63.67 A." @default.
- W2952185280 created "2019-06-27" @default.
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- W2952185280 date "2000-09-01" @default.
- W2952185280 modified "2023-10-18" @default.
- W2952185280 title "Hexagonal Nanoporous Host Structures Based on 2,4,6-Tris-4-(halo-phenoxy)-1,3,5-triazines (Halo=Chloro, Bromo)" @default.
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- W2952185280 doi "https://doi.org/10.1016/s0040-4020(00)00491-9" @default.
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