FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952192015> ?p ?o ?g. }

• W2952192015 endingPage "7857" @default.
• W2952192015 startingPage "7852" @default.
• W2952192015 abstract "Acetates derived from the adducts of the Baylis-Hillman reaction can be reacted in a regioselective manner with amines in the presence of palladium(0) catalyst to afford alpha-dehydro-beta-amino esters (2 and 3) in good yields. The regioselectivity of the reaction can be controlled by temperature and reaction medium leading to the synthesis of regioisomers 2 or 3. The alpha-dehydro-beta-amino acid 3 is a turn inducer, and the dipeptides 6 derived from it show the presence of an eight-membered intramolecular hydrogen bond. Also, cobalt(II) chloride catalyzes the cleavage of epoxy peptides with alpha-dehydro-beta-amino acid derivative 3b to afford the corresponding dipeptide derivatives 8, which exhibit an intramolecular hydrogen bond and thus mimic a beta-turn. This intramolecular hydrogen bonding preorganizes the corresponding diallylated peptide 8c for cyclization via ring-closing metathesis to afford the cyclic peptide 9 as a constrained mimic of a beta-turn." @default.
• W2952192015 created "2019-06-27" @default.
• W2952192015 creator A5017415148 @default.
• W2952192015 creator A5035750560 @default.
• W2952192015 creator A5038250843 @default.
• W2952192015 date "2002-10-03" @default.
• W2952192015 modified "2023-10-03" @default.
• W2952192015 title "Palladium(0)-Catalyzed Regioselective Synthesis of α-Dehydro-β-amino Esters from Amines and Allyl Acetates: Synthesis of a α-Dehydro-β-amino Acid Derived Cyclic Peptide as a Constrained β-Turn Mimic" @default.
• W2952192015 cites W1972764797 @default.
• W2952192015 cites W1986485529 @default.
• W2952192015 cites W1990437549 @default.
• W2952192015 cites W1995855261 @default.
• W2952192015 cites W2000328816 @default.
• W2952192015 cites W2012716149 @default.
• W2952192015 cites W2021017445 @default.
• W2952192015 cites W2037171320 @default.
• W2952192015 cites W2044893326 @default.
• W2952192015 cites W2045539797 @default.
• W2952192015 cites W2062053892 @default.
• W2952192015 cites W2079022876 @default.
• W2952192015 cites W2086320611 @default.
• W2952192015 cites W2088187525 @default.
• W2952192015 cites W2093561477 @default.
• W2952192015 cites W2109293738 @default.
• W2952192015 cites W2151261255 @default.
• W2952192015 cites W2414910545 @default.
• W2952192015 cites W2949692444 @default.
• W2952192015 cites W2950571911 @default.
• W2952192015 doi "https://doi.org/10.1021/jo010981d" @default.
• W2952192015 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/12398513" @default.
• W2952192015 hasPublicationYear "2002" @default.
• W2952192015 type Work @default.
• W2952192015 sameAs 2952192015 @default.
• W2952192015 citedByCount "73" @default.
• W2952192015 countsByYear W29521920152012 @default.
• W2952192015 countsByYear W29521920152013 @default.
• W2952192015 countsByYear W29521920152014 @default.
• W2952192015 countsByYear W29521920152015 @default.
• W2952192015 countsByYear W29521920152016 @default.
• W2952192015 countsByYear W29521920152017 @default.
• W2952192015 countsByYear W29521920152018 @default.
• W2952192015 countsByYear W29521920152019 @default.
• W2952192015 countsByYear W29521920152020 @default.
• W2952192015 countsByYear W29521920152023 @default.
• W2952192015 crossrefType "journal-article" @default.
• W2952192015 hasAuthorship W2952192015A5017415148 @default.
• W2952192015 hasAuthorship W2952192015A5035750560 @default.
• W2952192015 hasAuthorship W2952192015A5038250843 @default.
• W2952192015 hasConcept C108204754 @default.
• W2952192015 hasConcept C112887158 @default.
• W2952192015 hasConcept C153914509 @default.
• W2952192015 hasConcept C155647269 @default.
• W2952192015 hasConcept C161790260 @default.
• W2952192015 hasConcept C178790620 @default.
• W2952192015 hasConcept C185592680 @default.
• W2952192015 hasConcept C2779138802 @default.
• W2952192015 hasConcept C2779281246 @default.
• W2952192015 hasConcept C32909587 @default.
• W2952192015 hasConcept C44228677 @default.
• W2952192015 hasConcept C502130503 @default.
• W2952192015 hasConcept C515207424 @default.
• W2952192015 hasConcept C521977710 @default.
• W2952192015 hasConcept C55493867 @default.
• W2952192015 hasConcept C59759590 @default.
• W2952192015 hasConcept C71240020 @default.
• W2952192015 hasConcept C75079739 @default.
• W2952192015 hasConceptScore W2952192015C108204754 @default.
• W2952192015 hasConceptScore W2952192015C112887158 @default.
• W2952192015 hasConceptScore W2952192015C153914509 @default.
• W2952192015 hasConceptScore W2952192015C155647269 @default.
• W2952192015 hasConceptScore W2952192015C161790260 @default.
• W2952192015 hasConceptScore W2952192015C178790620 @default.
• W2952192015 hasConceptScore W2952192015C185592680 @default.
• W2952192015 hasConceptScore W2952192015C2779138802 @default.
• W2952192015 hasConceptScore W2952192015C2779281246 @default.
• W2952192015 hasConceptScore W2952192015C32909587 @default.
• W2952192015 hasConceptScore W2952192015C44228677 @default.
• W2952192015 hasConceptScore W2952192015C502130503 @default.
• W2952192015 hasConceptScore W2952192015C515207424 @default.
• W2952192015 hasConceptScore W2952192015C521977710 @default.
• W2952192015 hasConceptScore W2952192015C55493867 @default.
• W2952192015 hasConceptScore W2952192015C59759590 @default.
• W2952192015 hasConceptScore W2952192015C71240020 @default.
• W2952192015 hasConceptScore W2952192015C75079739 @default.
• W2952192015 hasIssue "22" @default.
• W2952192015 hasLocation W29521920151 @default.
• W2952192015 hasLocation W29521920152 @default.
• W2952192015 hasOpenAccess W2952192015 @default.
• W2952192015 hasPrimaryLocation W29521920151 @default.
• W2952192015 hasRelatedWork W2008473455 @default.
• W2952192015 hasRelatedWork W2020529032 @default.
• W2952192015 hasRelatedWork W2026957788 @default.
• W2952192015 hasRelatedWork W2049107280 @default.
• W2952192015 hasRelatedWork W2057153496 @default.
• W2952192015 hasRelatedWork W2061178681 @default.
• W2952192015 hasRelatedWork W2074706340 @default.
• W2952192015 hasRelatedWork W2528994491 @default.
• W2952192015 hasRelatedWork W2616113702 @default.

• next