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- W2952201625 abstract "Abstract The reduction of unprotected 5-bromo-5-deoxy- d -ribono, d -arabinono and d -xylono-1,4-lactones was achieved with NaBH 4 in water–EtOH. The corresponding 1-bromo-1-deoxypentitols were isolated after acetylation in good overall yields (60–90%). 1-Azido-1-deoxypentitols were obtained quantitatively either by nucleophilic substitution by azide ion and deacetylation of the corresponding monobromopentitols or by reduction of the corresponding 5-azido-5-deoxy- d -pentono-1,4-lactones. The reduction of the monoazidopentitols by catalytic hydrogen transfer gave the monoaminopentitol analogues in quantitative yield." @default.
- W2952201625 created "2019-06-27" @default.
- W2952201625 creator A5005326177 @default.
- W2952201625 creator A5039395684 @default.
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- W2952201625 date "2010-06-08" @default.
- W2952201625 modified "2023-10-18" @default.
- W2952201625 title "ChemInform Abstract: Efficient Syntheses of 1-Bromodeoxy-, 1-Azidodeoxy-, and 1-Aminodeoxypentitols from Unprotected D-Pentono-1,4-lactones." @default.
- W2952201625 cites W2088703617 @default.
- W2952201625 doi "https://doi.org/10.1002/chin.200018140" @default.
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