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- W2952202499 abstract "Abstract A new synthetic approach to silylated polyunsaturated halides has been developed, starting from the readily available (1 E ,3 E )-1,4-bis(trimethylsilyl)-1,3-butadiene and (3 E )-1,4-bis(trimethylsilyl)-3-buten-1-yne. A simple epoxidation reaction, followed by regioselective α-opening of the epoxide ring by metal halides affords the corresponding halohydrins with a high degree of stereoselectivity. A subsequent β-elimination reaction from these compounds leads to ( Z , E )-dienyl halides and to ( Z )-enyne halides." @default.
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- W2952202499 date "2001-05-08" @default.
- W2952202499 modified "2023-09-23" @default.
- W2952202499 title "ChemInform Abstract: A Stereoselective Synthesis of Silylated Polyunsaturated Halides from α,β-Epoxysilanes." @default.
- W2952202499 cites W2037294003 @default.
- W2952202499 doi "https://doi.org/10.1002/chin.200119035" @default.
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