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- W2952202833 abstract "In the absence of an allylic hydroxy group, the stereochemistry of hydroboration of an androst-4-ene is determined by the presence and stereochemistry of the C-10 methyl group. Allylic hydroxy groups at C-3 direct the hydroboration/oxidation to the anti-face. In the case of the 3α-alcohol, this effect is in opposition to the normal hydration from the α-face of the steroid and leads to the 4β-alcohol. The stereochemistry of 4β,17β-diacetoxy-19-nor-5β-androstane was established by X-ray crystallography." @default.
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- W2952202833 date "2010-08-13" @default.
- W2952202833 modified "2023-09-26" @default.
- W2952202833 title "ChemInform Abstract: Facial Selectivity in the Hydroboration of Androst-4-enes." @default.
- W2952202833 cites W1995171739 @default.
- W2952202833 doi "https://doi.org/10.1002/chin.199552201" @default.
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