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- W2952203058 abstract "A new practical route for the first total synthesis of (+)-homopumiliotoxin 223G is described, in which the palladium-catalyzed carbonylation of the vinyl iodide, leading to efficient construction of the quinolizidine nucleus incorporating the (Z)-alkylidene side chain, is the key strategic element. Another key feature of this synthesis involves the Lewis acid-induced chelation-controlled propargylation using the allenylsilane with complete diastereoselectivity." @default.
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- W2952203058 date "1998-04-01" @default.
- W2952203058 modified "2023-09-24" @default.
- W2952203058 title "Total synthesis of (+)-homopumiliotoxin 223G" @default.
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- W2952203058 doi "https://doi.org/10.1016/s0040-4039(98)00082-3" @default.
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