Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952206007> ?p ?o ?g. }
- W2952206007 endingPage "235" @default.
- W2952206007 startingPage "199" @default.
- W2952206007 abstract "Transition metal η2-vinyl complexes, LnM(η2-CRCR2), adopt structures in which both alkenyl carbons are bound to the metal. The M(CRCR2) unit is not planar in these 1-metallocyclopropene complexes. Instead, the CR2 entity is twisted by ca. 90° away from planarity with the three-membered ring formed by M, Cα, and Cβ. The ring carbons of η2-vinyl ligands are bound asymmetrically to the metal with one short metal–carbon bond and one long metal–carbon bond. These geometrical features reflect double bond character between Cα and the metal at the expense of the carbon–carbon double bond in the classic organic vinyl moiety. Coordination of both carbons of the four-electron donating η2-vinyl ligand increases the electron count at the metal by two electrons relative to an η1-bound vinyl ligand. This review summarizes synthetic methods which yield η2-vinyl complexes, describes bonding and structural characteristics of η2-vinyl ligands, tabulates NMR spectroscopic signatures of η2-vinyl ligands, and outlines reactions of this growing class of compounds." @default.
- W2952206007 created "2019-06-27" @default.
- W2952206007 creator A5018295014 @default.
- W2952206007 creator A5035990744 @default.
- W2952206007 date "2000-09-01" @default.
- W2952206007 modified "2023-09-29" @default.
- W2952206007 title "Transition metal η2-vinyl complexes" @default.
- W2952206007 cites W1585330505 @default.
- W2952206007 cites W1811563904 @default.
- W2952206007 cites W1828225620 @default.
- W2952206007 cites W1874907161 @default.
- W2952206007 cites W1965764244 @default.
- W2952206007 cites W1967673147 @default.
- W2952206007 cites W1970686302 @default.
- W2952206007 cites W1971884717 @default.
- W2952206007 cites W1973050643 @default.
- W2952206007 cites W1976030820 @default.
- W2952206007 cites W1979916360 @default.
- W2952206007 cites W1980042740 @default.
- W2952206007 cites W1981296295 @default.
- W2952206007 cites W1981612165 @default.
- W2952206007 cites W1984003433 @default.
- W2952206007 cites W1984250268 @default.
- W2952206007 cites W1985798198 @default.
- W2952206007 cites W1987813769 @default.
- W2952206007 cites W1990056093 @default.
- W2952206007 cites W1990537569 @default.
- W2952206007 cites W1990683541 @default.
- W2952206007 cites W1990756780 @default.
- W2952206007 cites W1990762394 @default.
- W2952206007 cites W1994203519 @default.
- W2952206007 cites W1995387931 @default.
- W2952206007 cites W1995923708 @default.
- W2952206007 cites W1996113203 @default.
- W2952206007 cites W1996807310 @default.
- W2952206007 cites W1999349796 @default.
- W2952206007 cites W2002525512 @default.
- W2952206007 cites W2003161626 @default.
- W2952206007 cites W2004790325 @default.
- W2952206007 cites W2005246225 @default.
- W2952206007 cites W2005486945 @default.
- W2952206007 cites W2005916468 @default.
- W2952206007 cites W2008583009 @default.
- W2952206007 cites W2009261506 @default.
- W2952206007 cites W2009839005 @default.
- W2952206007 cites W2010393422 @default.
- W2952206007 cites W2011646556 @default.
- W2952206007 cites W2013128113 @default.
- W2952206007 cites W2014813117 @default.
- W2952206007 cites W2014911859 @default.
- W2952206007 cites W2015756736 @default.
- W2952206007 cites W2016539311 @default.
- W2952206007 cites W2018422962 @default.
- W2952206007 cites W2019267795 @default.
- W2952206007 cites W2020120785 @default.
- W2952206007 cites W2020828037 @default.
- W2952206007 cites W2025009852 @default.
- W2952206007 cites W2025267150 @default.
- W2952206007 cites W2027171883 @default.
- W2952206007 cites W2030235168 @default.
- W2952206007 cites W2031864711 @default.
- W2952206007 cites W2031991734 @default.
- W2952206007 cites W2033862724 @default.
- W2952206007 cites W2035641682 @default.
- W2952206007 cites W2035918122 @default.
- W2952206007 cites W2036017555 @default.
- W2952206007 cites W2037565705 @default.
- W2952206007 cites W2040360819 @default.
- W2952206007 cites W2041522146 @default.
- W2952206007 cites W2042270262 @default.
- W2952206007 cites W2043005805 @default.
- W2952206007 cites W2043981712 @default.
- W2952206007 cites W2046476594 @default.
- W2952206007 cites W2047447362 @default.
- W2952206007 cites W2049197584 @default.
- W2952206007 cites W2050671140 @default.
- W2952206007 cites W2051443187 @default.
- W2952206007 cites W2053405551 @default.
- W2952206007 cites W2056860864 @default.
- W2952206007 cites W2057866662 @default.
- W2952206007 cites W2061143905 @default.
- W2952206007 cites W2062838765 @default.
- W2952206007 cites W2065197912 @default.
- W2952206007 cites W2068805874 @default.
- W2952206007 cites W2069497963 @default.
- W2952206007 cites W2070138717 @default.
- W2952206007 cites W2074644034 @default.
- W2952206007 cites W2079175013 @default.
- W2952206007 cites W2082945353 @default.
- W2952206007 cites W2085831044 @default.
- W2952206007 cites W2088783203 @default.
- W2952206007 cites W2090141747 @default.
- W2952206007 cites W2091939057 @default.
- W2952206007 cites W2092424724 @default.
- W2952206007 cites W2093071678 @default.
- W2952206007 cites W2101631127 @default.
- W2952206007 cites W2104559507 @default.
- W2952206007 cites W2151383983 @default.