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- W2952206095 abstract "Cobalt–chiral diphoshine catalytic systems promote intramolecular hydroacylation reactions of 2-acylbenzaldehydes and 2-alkenylbenzaldehydes to afford phthalide and indanone derivatives, respectively, in moderate to good yields with high enantioselectivities. The ketone hydroacylation did not exhibit a significant H/D kinetic isotope effect (KIE) with respect to the aldehyde C–H bond, indicating that C–H activation would not be involved in the rate-limiting step." @default.
- W2952206095 created "2019-06-27" @default.
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- W2952206095 date "2015-05-15" @default.
- W2952206095 modified "2023-09-26" @default.
- W2952206095 title "ChemInform Abstract: Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins." @default.
- W2952206095 cites W2331395067 @default.
- W2952206095 doi "https://doi.org/10.1002/chin.201522024" @default.
- W2952206095 hasPublicationYear "2015" @default.
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