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- W2952208045 abstract "A catalytic tandem arylation–cyclization approach using 2-alkynylphenyl isothiocyanates with diaryliodonium salts is described. The reaction is performed under mild conditions and thiochromeno[2,3-b]indoles are obtained in moderate to good yields. This tandem protocol involves chemoselective S-arylation, regioselective 5-endo-trig cyclization and Friedel–Crafts-type cyclization processes. Two C–C bonds, one C–S bond, and two heterocyclic rings are formed in a single step. Preliminary mechanistic studies indicate that a carbocation mechanism is involved." @default.
- W2952208045 created "2019-06-27" @default.
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- W2952208045 date "2016-10-01" @default.
- W2952208045 modified "2023-09-27" @default.
- W2952208045 title "ChemInform Abstract: Copper-Catalyzed Tandem Arylation-Cyclization of 2-Alkynylaryl Isothiocyanates with Diaryliodonium Salts: An Efficient Synthesis of Thiochromeno[2,3-b]indoles." @default.
- W2952208045 cites W2398432750 @default.
- W2952208045 doi "https://doi.org/10.1002/chin.201645119" @default.
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