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- W2952209766 abstract "Catalytic assembly of enantiopure aliphatic amines from abundant and readily available precursors has long been recognized as a paramount challenge in synthetic chemistry. Here, we describe a mild and general copper-catalyzed hydroamination that effectively converts unactivated internal olefins—an important yet unexploited class of abundant feedstock chemicals—into highly enantioenriched a-branched amines (≥96% enantiomeric excess) featuring two minimally differentiated aliphatic substituents. This method provides a powerful means to access a broad range of advanced, highly functionalized enantioenriched amines of interest in pharmaceutical research and other areas." @default.
- W2952209766 created "2019-06-27" @default.
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- W2952209766 date "2015-07-01" @default.
- W2952209766 modified "2023-09-27" @default.
- W2952209766 title "Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines" @default.
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