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- W2952209887 abstract "Trimethylsilyl and DBU nitronates derived from nitromethane and nitropropanes do not undergoC-alkylation by episulfonium (ESI) or thiophanium (TPI) cationic intermediates. The above-mentioned derivatives of 1-nitropropane react with ESI and TPI to give the corresponding products ofO-alkylation of 1-chloro-1-oxyiminopropane. The reactions of DBU nitronates derived from nitromethane and 2-nitropropane with ESI or TPI proceed asO-alkylation followed by standard fragmentation of the initially formed nitronate intermediates to give methyl (4-tolylthio)acetate or methyl 2,2-dimethyl-3-methyloxy-(4-tolylthio)butanoate respectively." @default.
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- W2952209887 date "2010-06-12" @default.
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- W2952209887 title "ChemInform Abstract: Reactions of Nitronates Derived from Simple Nitro Alkanes with Some Thio-Stabilized Cationic Intermediates." @default.
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- W2952209887 doi "https://doi.org/10.1002/chin.199945087" @default.
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