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- W2952209946 abstract "Abstract Reaction of [(η 5 -C 5 H 5 )Ru(PPh 3 ) 2 Cl] ( 1 ) with sodium nitrite in hot acidified ehtanol followed by anion exchange gave the red crystalline solid [(η 5 -C 5 H 5 )Ru(PPh 3 (NO)(Cl]PF 6 ( 2 ) in good yield. Compound 2 has been crystallographically characterised and shows a large interligand angle at ruthenium between the chloride and nitrosyl ligands. The dication {[(η 5 -C 5 H 5 )Ru(PPh 3 )(CN t Bu)(NO)][BF 4 ] 2 } ( 4 ) has been prepared from [(η 5 -C 5 H 5 )Ru(PPh 3 )(CN t Bu)(Cl)] ( 3 ) and nitrosinium tetrafluoroborate." @default.
- W2952209946 created "2019-06-27" @default.
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- W2952209946 date "2010-08-23" @default.
- W2952209946 modified "2023-09-25" @default.
- W2952209946 title "ChemInform Abstract: Synthesis and Crystal Structure of the Six-Coordinate Ruthenium Nitrosyl Complex ((η5-C5H5)Ru(PPh3)(NO)(Cl))PF6." @default.
- W2952209946 cites W2005675040 @default.
- W2952209946 doi "https://doi.org/10.1002/chin.199110265" @default.
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