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- W2952227159 abstract "The title compound is synthesized by direct fusion of the elements at 400 C followed by annealing at 330 C, quenching to room temperature, and subsequent annealing at 120 and 100 C for days to weeks. The compound crystallizes in the monoclinic space group P2{sub 1}/c (No. 14), with Z = 4, a = 10.132(1){angstrom}, b = 22.323(2){angstrom}, c = 13.376(1){angstrom}, and {beta} = 93.14(1){degree}, and consists of Tl{sub 7}{sup 7{minus}} clusters embedded in a matrix of potassium ions. The cluster is an axially compressed pentagonal bipyramid close to D{sub 5h} symmetry. The apex-apex bond distance (3.462(1){angstrom}) is little longer than the bonds in the pentagonal waist (3.183(1)--3.247(1){angstrom}). Structurally the compound is not electron-precise: K{sub 10}Tl{sub 7} has three extra electrons per Tl{sub 7} cluster and is Pauli paramagnetic ({chi}{sub 300} = 2.25 x 10{sup {minus}4} emu/mol)." @default.
- W2952227159 created "2019-06-27" @default.
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- W2952227159 date "2010-06-08" @default.
- W2952227159 modified "2023-09-23" @default.
- W2952227159 title "ChemInform Abstract: Synthesis and Structure of K10Tl7: The First Binary Trielide Containing Naked Pentagonal Bipyramidal Tl7 Clusters." @default.
- W2952227159 cites W1981373638 @default.
- W2952227159 doi "https://doi.org/10.1002/chin.200021008" @default.
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