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• W2952231273 abstract "Trends in Fe−L bond distances in [Fe4S4L4]2-,3- cubane-type clusters with L = Cl- and RS- are summarized. The compound (Et4N)3[Fe4S4(SH)4]·Et4NCl was prepared and structurally characterized. The Fe−SH bond lengths of this cluster and previously reported (Ph4P)2[Fe4S4(SH)4] fall in the ranges for clusters with alkyl- and arenethiolate terminal ligands. Upon slow crystallization from 1,2-dichloroethane/THF, the compound (Pr4N)2[Fe4S4(SH)4] undergoes chloride substitution to form (Pr4N)2[Fe4S4Cl4], which may be identified by its Fe−Cl distance. An X-ray structure recently attributed to (Pr4N)2[Fe4S4(SH)4] is that of (Pr4N)2[Fe4S4Cl4]." @default.
• W2952231273 created "2019-06-27" @default.
• W2952231273 creator A5015760741 @default.
• W2952231273 creator A5052881048 @default.
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• W2952231273 date "1998-05-30" @default.
• W2952231273 modified "2023-09-24" @default.
• W2952231273 title "Terminal Ligand Assignments Based on Trends in Metal−Ligand Bond Lengths of Cubane-Type [Fe₄S₄]^2+,+ Clusters" @default.
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• W2952231273 doi "https://doi.org/10.1021/ic980092h" @default.
• W2952231273 hasPublicationYear "1998" @default.
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