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- W2952237662 abstract "A flexible enantioselective route to highly functionalized α,β-unsaturated δ-lactones has allowed for the syntheses of the styryllactones: isoaltholactone, 3-epi-altholactone, and 5-hydroxygoniothalamin in 10%, 5%, and 13% overall yields from furfural, respectively. This approach derives its asymmetry by applying the Sharpless catalytic asymmetric dihydroxylation to vinylfuran. The resulting diols are produced in high enantioexcess and can be stereoselectively transformed into α,β-unsaturated δ-lactones via a short highly diastereoselective oxidation and reduction sequence." @default.
- W2952237662 created "2019-06-27" @default.
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- W2952237662 date "2000-08-23" @default.
- W2952237662 modified "2023-10-09" @default.
- W2952237662 title "Enantioselective Syntheses of Isoaltholactone, 3-<i>epi</i>-Altholactone, and 5-Hydroxygoniothalamin" @default.
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- W2952237662 doi "https://doi.org/10.1021/ol000179i" @default.
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