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- W2952252308 abstract "Studies of the quenching of aromatic hydrocarbon fluorescence by aromatic nitriles and 1,2,4-trimethoxybenzene in various solvents are presented and discussed with reference to the earlier experimental work of Rehm and Weller. The kinetic behaviour observed in the quenching by aromatic nitriles is not consistent with that observed in previous work. The quenching rate constants and activation parameters for ethanol solution appear to be independent of the free-energy change for electron transfer until strong exciplex interactions become possible, at which point the mechanism rapidly changes to one of diffusion-controlled exciplex formation and decay. 1,2,4-trimethoxybenzene quenches pyrene fluorescence with a rate constant which is consistent with Rehm and Weller's correlation with ΔG⊖, but the reaction has Arrhenius parameters indicative of excited-complex formation, rather than direct electron transfer." @default.
- W2952252308 created "2019-06-27" @default.
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- W2952252308 date "1983-04-12" @default.
- W2952252308 modified "2023-09-27" @default.
- W2952252308 title "ChemInform Abstract: ELECTRON DONOR-ACCEPTOR INTERACTIONS IN THE QUENCHING OF AROMATIC HYDROCARBON FLUORESCENCE. THE EFFECTS OF TEMPERATURE AND SOLVENT PERMITTIVITY" @default.
- W2952252308 cites W1983960415 @default.
- W2952252308 doi "https://doi.org/10.1002/chin.198315053" @default.
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