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- W2952271366 abstract "A highly efficient Mukaiyama aldol reaction between ketones and trimethylsilyl enolates catalyzed by sodium phenoxide-phosphine oxides as simple homogeneous Lewis base catalysts (0.5-10 mol %) was developed, which minimized competing retro-aldol reaction. For a variety of aromatic ketones and aldimines, aldol and Mannich-type products with an alpha-quaternary carbon center were obtained in good to excellent yields. Up to 100 mmol scale of benzophenone and trimethylsilyl enolate with 0.5 mol % of catalyst was established in 97% yield (34.8 g)." @default.
- W2952271366 created "2019-06-27" @default.
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- W2952271366 date "2008-03-25" @default.
- W2952271366 modified "2023-09-26" @default.
- W2952271366 title "ChemInform Abstract: Sodium Phenoxide—Phosphine Oxides as Extremely Active Lewis Base Catalysts for the Mukaiyama Aldol Reaction with Ketones." @default.
- W2952271366 cites W2144502181 @default.
- W2952271366 doi "https://doi.org/10.1002/chin.200813043" @default.
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