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- W2952278078 abstract "Stereoselective reductions of (S)-4-isopropyl-3-phenacyl-1, 3-oxazolidin-2-one (2) with several complex metal hydrides gave 2-4'-isopropyl-2'-oxo-1', 3'-oxazolidinyl-1-phenylethanol (3) and 2-N-1'-isopropyl-2'-hydroxyethyl-N-methylamino-1-phenylethanol (4) in good yields. These products were diastereomeric mixtures and the diastereomer ratios were estimated to be ca. 75 : 25. The asymmetric 2-amino-1-phenylethanols (major products of 3 and 4) were easily isolated by recrystallization. The absolute configuration of (1S, 4'S)-3 was determined by X-ray analysis. The reductions of (S)-4-isopropyl-1-phenacyl-1, 3-oxazolidine (6) with complex metal hydrides gave 2-4'-isopropyl-1', 3'-oxazolidinyl-1-phenylethanol (7) and 4 as diastereomeric mixtures (ca. 70 : 30)." @default.
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- W2952278078 date "1985-07-02" @default.
- W2952278078 modified "2023-09-24" @default.
- W2952278078 title "ChemInform Abstract: STEREOSELECTIVE REDUCTION OF (S)-4-ISOPROPYL-3-PHENACYL-1,3-OXAZOLIDIN-2-ONE BY MEANS OF 1,4-ASYMMETRIC INDUCTION: SYNTHESIS OF CHIRAL 2-AMINO-1-PHENYLETHANOLS" @default.
- W2952278078 cites W1531451581 @default.
- W2952278078 doi "https://doi.org/10.1002/chin.198526165" @default.
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