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- W2952298894 abstract "Under boiling and refluxing conditions, molecular hydrogen was evolved was evolved catalytically, without photoirradiation, from cyclo- and n-alkanes using Wilkinson complexes. In the presence of hydrogen acceptors such as alkenes, hydrogen transfer rather than hydrogen evolution occurred. The rates of both reactions using the Wilkinson complex [RhCl(PR3)3], R = aryl, were comparable, however, when R = alkyl, the rate of hydrogen evolution was reduced more effectively than that of hydrogen transfer. The mechanisms of the thermocatalytic dehydrogenation of the alkanes using these complexes are discussed in terms of electron-accepting or -donating ligand properties." @default.
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- W2952298894 date "2010-08-20" @default.
- W2952298894 modified "2023-09-26" @default.
- W2952298894 title "ChemInform Abstract: Thermocatalytic Dehydrogenation of Alkanes with Wilkinson Complexes" @default.
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- W2952298894 doi "https://doi.org/10.1002/chin.199324100" @default.
- W2952298894 hasPublicationYear "2010" @default.
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