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- W2952313294 endingPage "857" @default.
- W2952313294 startingPage "838" @default.
- W2952313294 abstract "High-valent metalloporphyrin intermediates have been implicated as key players in numerous mechanistic proposals for both biological (e.g., heme protein) and synthetic porphyrin mediated transformations. However, the direct observation of these species is quite challenging because of the inherently short lifetimes of many of these metalloporphyrin intermediates. This review focuses on our own efforts to synthesize and study a new class of porphyrinoid compounds called corrolazines, which are designed to stabilize high-valent species for direct analysis. These compounds are related to corroles, which also exhibit the unusual ability to stabilize high oxidation states, and the reactivity and physical properties of relevant corrole and porphyrin analogs are compared with the appropriate corrolazines. The chemistry of Cu, Co, V, and Mn are highlighted, with a particular emphasis on the reactivity of high-valent manganese-oxo complexes." @default.
- W2952313294 created "2019-06-27" @default.
- W2952313294 creator A5035006133 @default.
- W2952313294 creator A5039632340 @default.
- W2952313294 date "2006-04-01" @default.
- W2952313294 modified "2023-09-27" @default.
- W2952313294 title "High-valent transition metal corrolazines" @default.
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