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- W2952313615 abstract "Lewis acid-catalyzed reaction of acetals with allenylsilanes and the three-component reactions of aldehydes, alkoxysilanes, and allenylsilanes are described. Both reactions are strongly dependent on the substituent at the α-position of allenylsilanes. Allenylsilanes having bulky substituents such as the tert-butyl and isopropyl groups result in the corresponding α-propargyl ethers in high yields, whereas allenylsilanes having the methyl and ethyl groups afford not only the corresponding α-propargyl ethers in low yield but also cyclopropyl ketones and α,β-unsaturated ketones as by-products." @default.
- W2952313615 created "2019-06-27" @default.
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- W2952313615 date "2002-01-01" @default.
- W2952313615 modified "2023-10-16" @default.
- W2952313615 title "Lewis acid-catalyzed three-component condensation reactions of aldehydes, alkoxysilanes, and allenylsilanes: synthesis of α-propargyl ethers" @default.
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- W2952313615 doi "https://doi.org/10.1016/s0040-4020(01)01145-0" @default.
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