Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952319942> ?p ?o ?g. }
Showing items 1 to 61 of
61
with 100 items per page.
- W2952319942 abstract "A Personal Account describing the enantioselective total syntheses of cyathane diterpenoids achieved in the Nakada group. A convergent approach to the cyathane scaffold, the [5-6-7] tricyclic carbon skeleton commonly found in cyathane diterpenoids, has been developed using the catalytic asymmetric intramolecular cyclopropanation (CAIMCP) and baker's yeast reduction. This approach has been successfully applied for the enantioselective total syntheses of (+)-allocyathin B2 , (-)-erinacine B, and (-)-erinacine E. The total synthesis of (-)-erinacine E has been achieved via the acyl group migratory intramolecular aldol reaction, which prevents the retro-aldol reaction and allows the construction of the strained structure. The highly efficient and stereoselective total syntheses of (-)-scabronines G, A, D, and (-)-episcabronine A have been achieved via the oxidative dearomatization/inverse electron demand Diels-Alder reaction cascade. Cascade reactions comprising three and five consecutive reactions were employed for the highly efficient total syntheses of (-)-scabronine A and (-)-episcabronine A, respectively." @default.
- W2952319942 created "2019-06-27" @default.
- W2952319942 creator A5046876098 @default.
- W2952319942 date "2014-11-13" @default.
- W2952319942 modified "2023-09-27" @default.
- W2952319942 title "ChemInform Abstract: Enantioselective Total Syntheses of Cyathane Diterpenoids" @default.
- W2952319942 cites W1502525322 @default.
- W2952319942 doi "https://doi.org/10.1002/chin.201448235" @default.
- W2952319942 hasPublicationYear "2014" @default.
- W2952319942 type Work @default.
- W2952319942 sameAs 2952319942 @default.
- W2952319942 citedByCount "0" @default.
- W2952319942 crossrefType "journal-article" @default.
- W2952319942 hasAuthorship W2952319942A5046876098 @default.
- W2952319942 hasConcept C146686406 @default.
- W2952319942 hasConcept C161790260 @default.
- W2952319942 hasConcept C178790620 @default.
- W2952319942 hasConcept C181647583 @default.
- W2952319942 hasConcept C185592680 @default.
- W2952319942 hasConcept C2777052750 @default.
- W2952319942 hasConcept C35753019 @default.
- W2952319942 hasConcept C61156836 @default.
- W2952319942 hasConcept C71240020 @default.
- W2952319942 hasConcept C75079739 @default.
- W2952319942 hasConceptScore W2952319942C146686406 @default.
- W2952319942 hasConceptScore W2952319942C161790260 @default.
- W2952319942 hasConceptScore W2952319942C178790620 @default.
- W2952319942 hasConceptScore W2952319942C181647583 @default.
- W2952319942 hasConceptScore W2952319942C185592680 @default.
- W2952319942 hasConceptScore W2952319942C2777052750 @default.
- W2952319942 hasConceptScore W2952319942C35753019 @default.
- W2952319942 hasConceptScore W2952319942C61156836 @default.
- W2952319942 hasConceptScore W2952319942C71240020 @default.
- W2952319942 hasConceptScore W2952319942C75079739 @default.
- W2952319942 hasLocation W29523199421 @default.
- W2952319942 hasOpenAccess W2952319942 @default.
- W2952319942 hasPrimaryLocation W29523199421 @default.
- W2952319942 hasRelatedWork W1970830746 @default.
- W2952319942 hasRelatedWork W1991656464 @default.
- W2952319942 hasRelatedWork W2027127570 @default.
- W2952319942 hasRelatedWork W2049395751 @default.
- W2952319942 hasRelatedWork W2063180270 @default.
- W2952319942 hasRelatedWork W2139583920 @default.
- W2952319942 hasRelatedWork W2396033722 @default.
- W2952319942 hasRelatedWork W2949121712 @default.
- W2952319942 hasRelatedWork W2949222013 @default.
- W2952319942 hasRelatedWork W2949850837 @default.
- W2952319942 hasRelatedWork W2950149379 @default.
- W2952319942 hasRelatedWork W2950336917 @default.
- W2952319942 hasRelatedWork W2950755625 @default.
- W2952319942 hasRelatedWork W2951129120 @default.
- W2952319942 hasRelatedWork W2951492180 @default.
- W2952319942 hasRelatedWork W2951672280 @default.
- W2952319942 hasRelatedWork W2951787046 @default.
- W2952319942 hasRelatedWork W2952525806 @default.
- W2952319942 hasRelatedWork W2952687349 @default.
- W2952319942 hasRelatedWork W2952808580 @default.
- W2952319942 isParatext "false" @default.
- W2952319942 isRetracted "false" @default.
- W2952319942 magId "2952319942" @default.
- W2952319942 workType "article" @default.