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- W2952324103 abstract "The decomposition of 1-chloro-1,1-difluoroethane by a radical chain reaction has been studied in a flow reactor in the temperature range from 503 to 773 K. For the initiation of the chain small amounts of added chlorine were photolyzed with a XeCl laser (λ = 308 nm). The formation of the dehydrochlorination and chlorination products, vinylidene fluoride, and 1,2-dichloro-1,1-difluoroethane respectively, is described by a kinetic model. Arrhenius parameters for the two abstraction reactions and were determined by a competition method: Experimental and modeling results are discussed with respect to former studies on the thermal reaction of 1-chloro-1,1-difluoroethane." @default.
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- W2952324103 date "1989-09-05" @default.
- W2952324103 modified "2023-10-15" @default.
- W2952324103 title "ChemInform Abstract: Kinetics of UV-Laser Induced Dehydrochlorination of 1-Chloro-1,1-difluoroethane" @default.
- W2952324103 cites W2013899332 @default.
- W2952324103 doi "https://doi.org/10.1002/chin.198936135" @default.
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