Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952327218> ?p ?o ?g. }
Showing items 1 to 69 of
69
with 100 items per page.
- W2952327218 abstract "An efficient and diastereoselective (CDC)–Rh-catalyzed hydroalkylation of dienes with 1,3-oxazol-5(4H)-ones is reported. Aryl and alkyl substituted dienes are converted to α,α-substituted oxazolones (24 examples) by the formation of N-substituted quaternary carbon stereogenic centers in good yields (up to 96%) and with high diastereoselectivity (>20 : 1 dr). The reaction is tolerant of a range of dienes and oxazolones bearing various functional groups. Utility of the oxazolone products is illustrated through hydrolysis to form α,β-substituted α-amino acid analogues and stereoselective epoxidation of the resultant alkene to create four contiguous stereocenters." @default.
- W2952327218 created "2019-06-27" @default.
- W2952327218 creator A5057740779 @default.
- W2952327218 creator A5065433340 @default.
- W2952327218 date "2016-09-01" @default.
- W2952327218 modified "2023-09-27" @default.
- W2952327218 title "ChemInform Abstract: Diastereoselective Synthesis of Vicinal Tertiary and N-Substituted Quaternary Stereogenic Centers by Catalytic Hydroalkylation of Dienes." @default.
- W2952327218 cites W2294965396 @default.
- W2952327218 doi "https://doi.org/10.1002/chin.201639020" @default.
- W2952327218 hasPublicationYear "2016" @default.
- W2952327218 type Work @default.
- W2952327218 sameAs 2952327218 @default.
- W2952327218 citedByCount "0" @default.
- W2952327218 crossrefType "journal-article" @default.
- W2952327218 hasAuthorship W2952327218A5057740779 @default.
- W2952327218 hasAuthorship W2952327218A5065433340 @default.
- W2952327218 hasConcept C121349320 @default.
- W2952327218 hasConcept C134195300 @default.
- W2952327218 hasConcept C146686406 @default.
- W2952327218 hasConcept C155647269 @default.
- W2952327218 hasConcept C161790260 @default.
- W2952327218 hasConcept C178790620 @default.
- W2952327218 hasConcept C181647583 @default.
- W2952327218 hasConcept C185592680 @default.
- W2952327218 hasConcept C2776254738 @default.
- W2952327218 hasConcept C2779790080 @default.
- W2952327218 hasConcept C2780263894 @default.
- W2952327218 hasConcept C2781076698 @default.
- W2952327218 hasConcept C71240020 @default.
- W2952327218 hasConceptScore W2952327218C121349320 @default.
- W2952327218 hasConceptScore W2952327218C134195300 @default.
- W2952327218 hasConceptScore W2952327218C146686406 @default.
- W2952327218 hasConceptScore W2952327218C155647269 @default.
- W2952327218 hasConceptScore W2952327218C161790260 @default.
- W2952327218 hasConceptScore W2952327218C178790620 @default.
- W2952327218 hasConceptScore W2952327218C181647583 @default.
- W2952327218 hasConceptScore W2952327218C185592680 @default.
- W2952327218 hasConceptScore W2952327218C2776254738 @default.
- W2952327218 hasConceptScore W2952327218C2779790080 @default.
- W2952327218 hasConceptScore W2952327218C2780263894 @default.
- W2952327218 hasConceptScore W2952327218C2781076698 @default.
- W2952327218 hasConceptScore W2952327218C71240020 @default.
- W2952327218 hasLocation W29523272181 @default.
- W2952327218 hasOpenAccess W2952327218 @default.
- W2952327218 hasPrimaryLocation W29523272181 @default.
- W2952327218 hasRelatedWork W2038357022 @default.
- W2952327218 hasRelatedWork W2080421316 @default.
- W2952327218 hasRelatedWork W2118579183 @default.
- W2952327218 hasRelatedWork W2119527404 @default.
- W2952327218 hasRelatedWork W2142311726 @default.
- W2952327218 hasRelatedWork W2294965396 @default.
- W2952327218 hasRelatedWork W2405082481 @default.
- W2952327218 hasRelatedWork W2515635485 @default.
- W2952327218 hasRelatedWork W2610347528 @default.
- W2952327218 hasRelatedWork W2792146314 @default.
- W2952327218 hasRelatedWork W2888569894 @default.
- W2952327218 hasRelatedWork W2949896294 @default.
- W2952327218 hasRelatedWork W2950787289 @default.
- W2952327218 hasRelatedWork W2951359765 @default.
- W2952327218 hasRelatedWork W2951786677 @default.
- W2952327218 hasRelatedWork W2952433559 @default.
- W2952327218 hasRelatedWork W2952827253 @default.
- W2952327218 hasRelatedWork W2953377502 @default.
- W2952327218 hasRelatedWork W2972626411 @default.
- W2952327218 hasRelatedWork W3105815128 @default.
- W2952327218 isParatext "false" @default.
- W2952327218 isRetracted "false" @default.
- W2952327218 magId "2952327218" @default.
- W2952327218 workType "article" @default.