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- W2952327596 abstract "In the reaction of the enolates of (Z)-N-[bis(methylthio)methylene]-α,β-didehydroglutamates with aldehydes, the retroaldolization process is faster than the aldol reaction, thus inhibiting the obtainment of the desired targets 6. However, in the presence of TMS−Cl as trapping agent, the equilibrium can be deplaced and the aldols 6 are obtained in the form of their TMS-derivatives 8. In the presence of BF3 or TBAF, either the syn or the anti adducts can be selectively obtained with good yields and diastereoselectivities." @default.
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- W2952327596 date "1998-11-01" @default.
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- W2952327596 title "Diastereoselective Aldol Reactions of (<i>Z</i>)-<i>N</i>-[Bis(methylthio)methylene]-α,β-didehydroglutamates" @default.
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