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- W2952330392 abstract "The oxidation of Tl+ by OH˙ radicals leads to an addition product [Tl(OH)]+ which exists in the equilibria [Tl(OH)]+⇌ Tl2++[OH]– and Tl[OH]2⇌[Tl(OH)]++[OH]–. The previously unrecorded pK of the latter equilibrium has been determined as 7.7 ± 0.2. The optical-absorption spectrum of Tl[OH]2 shows a maximum at 370 nm (Iµ 3.8 × 103 dm3 mol–1 cm–1) and a band rising towards the u.v. below 300 nm. Thallium(II) hydroxide, in contrast to Tl2+ and [Tl(OH)]+, does not exhibit good oxidizing properties. It may even transfer an electron to suitable acceptors such as tetrantromethane." @default.
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- W2952330392 date "1977-02-01" @default.
- W2952330392 modified "2023-09-24" @default.
- W2952330392 title "ChemInform Abstract: ON THE EQUILIBRIUM BETWEEN THALLIUM(II) HYDROXIDE AND HYDROXOTHALLIUM(II) ION- A PULSE-RADIOLYSIS STUDY" @default.
- W2952330392 cites W2015254702 @default.
- W2952330392 doi "https://doi.org/10.1002/chin.197705027" @default.
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