Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952330900> ?p ?o ?g. }
Showing items 1 to 75 of
75
with 100 items per page.
- W2952330900 abstract "[reaction: see text] The conjugate addition reaction of a stable, in situ generated silyllithium gives a beta-hydroxysilyl ester with high diastereoselectivity. Conversion of the beta-hydroxysilyl ester to a beta-fluorosilyl ester affords the precursor to the oxasilacyclopentane acetal in high yields under mild conditions. A hydride reduction and subsequent intramolecular silylation lead to the acetal in excellent yields. Finally, highly selective nucleophilic substitution affords oxasilacyclopentanes, which undergo a mild oxidation to afford 1,3-trans diols with high selectivity." @default.
- W2952330900 created "2019-06-27" @default.
- W2952330900 creator A5030139772 @default.
- W2952330900 creator A5076723798 @default.
- W2952330900 date "2004-03-23" @default.
- W2952330900 modified "2023-09-26" @default.
- W2952330900 title "Use of an Aminosilyllithium for the Diastereoselective Synthesis of Diphenyl Oxasilacyclopentane Acetals and Polyols." @default.
- W2952330900 cites W2128690830 @default.
- W2952330900 doi "https://doi.org/10.1002/chin.200412079" @default.
- W2952330900 hasPublicationYear "2004" @default.
- W2952330900 type Work @default.
- W2952330900 sameAs 2952330900 @default.
- W2952330900 citedByCount "0" @default.
- W2952330900 crossrefType "journal-article" @default.
- W2952330900 hasAuthorship W2952330900A5030139772 @default.
- W2952330900 hasAuthorship W2952330900A5076723798 @default.
- W2952330900 hasBestOaLocation W29523309002 @default.
- W2952330900 hasConcept C118792377 @default.
- W2952330900 hasConcept C134306372 @default.
- W2952330900 hasConcept C135731615 @default.
- W2952330900 hasConcept C155647269 @default.
- W2952330900 hasConcept C161790260 @default.
- W2952330900 hasConcept C178790620 @default.
- W2952330900 hasConcept C178907741 @default.
- W2952330900 hasConcept C185592680 @default.
- W2952330900 hasConcept C197336794 @default.
- W2952330900 hasConcept C2777731525 @default.
- W2952330900 hasConcept C2777961443 @default.
- W2952330900 hasConcept C33923547 @default.
- W2952330900 hasConcept C5304478 @default.
- W2952330900 hasConcept C544153396 @default.
- W2952330900 hasConcept C75079739 @default.
- W2952330900 hasConceptScore W2952330900C118792377 @default.
- W2952330900 hasConceptScore W2952330900C134306372 @default.
- W2952330900 hasConceptScore W2952330900C135731615 @default.
- W2952330900 hasConceptScore W2952330900C155647269 @default.
- W2952330900 hasConceptScore W2952330900C161790260 @default.
- W2952330900 hasConceptScore W2952330900C178790620 @default.
- W2952330900 hasConceptScore W2952330900C178907741 @default.
- W2952330900 hasConceptScore W2952330900C185592680 @default.
- W2952330900 hasConceptScore W2952330900C197336794 @default.
- W2952330900 hasConceptScore W2952330900C2777731525 @default.
- W2952330900 hasConceptScore W2952330900C2777961443 @default.
- W2952330900 hasConceptScore W2952330900C33923547 @default.
- W2952330900 hasConceptScore W2952330900C5304478 @default.
- W2952330900 hasConceptScore W2952330900C544153396 @default.
- W2952330900 hasConceptScore W2952330900C75079739 @default.
- W2952330900 hasLocation W29523309001 @default.
- W2952330900 hasLocation W29523309002 @default.
- W2952330900 hasOpenAccess W2952330900 @default.
- W2952330900 hasPrimaryLocation W29523309001 @default.
- W2952330900 hasRelatedWork W2006383543 @default.
- W2952330900 hasRelatedWork W2032476030 @default.
- W2952330900 hasRelatedWork W2108484195 @default.
- W2952330900 hasRelatedWork W2128561064 @default.
- W2952330900 hasRelatedWork W2949237038 @default.
- W2952330900 hasRelatedWork W2949428535 @default.
- W2952330900 hasRelatedWork W2949668237 @default.
- W2952330900 hasRelatedWork W2949910530 @default.
- W2952330900 hasRelatedWork W2949980549 @default.
- W2952330900 hasRelatedWork W2950154224 @default.
- W2952330900 hasRelatedWork W2950381990 @default.
- W2952330900 hasRelatedWork W2950794879 @default.
- W2952330900 hasRelatedWork W2951008693 @default.
- W2952330900 hasRelatedWork W2951413398 @default.
- W2952330900 hasRelatedWork W2952204699 @default.
- W2952330900 hasRelatedWork W2953015555 @default.
- W2952330900 hasRelatedWork W2953023362 @default.
- W2952330900 hasRelatedWork W2953053270 @default.
- W2952330900 hasRelatedWork W3083354843 @default.
- W2952330900 hasRelatedWork W2118520897 @default.
- W2952330900 isParatext "false" @default.
- W2952330900 isRetracted "false" @default.
- W2952330900 magId "2952330900" @default.
- W2952330900 workType "article" @default.