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- W2952332006 abstract "The syntheses and X-ray structures of very large polycyclic aromatic compounds containing clefts defined by polyphenylaryl groups are described. The C2-symmetric “albatrossenes” 1,3-bis(heptaphenyl-2-naphthyl)benzene (7a) and 1,3-bis(heptaphenyl-1-naphthyl)benzene (12a), as well as brominated derivatives, were synthesized by the addition of tetraphenylbenzyne to the appropriate polyphenyl biscyclopentadienones. The 2-naphthyl isomers have wide, shallow clefts, and the 1-naphthyl isomers have deep, narrow clefts which were observed to change size dramatically in different crystal environments. In a similar way, 1,3,5-tris(pentaphenylphenyl)benzene (19), a D3-symmetric molecular propeller with a diameter of 21 A, and 1,3,5-tris(heptaphenyl-2-naphthyl)benzene (22) were prepared by the addition of diphenylacetylene and tetraphenylbenzyne, respectively, to a triscyclopentadienone." @default.
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- W2952332006 date "1997-08-01" @default.
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- W2952332006 title "The Albatrossenes: Large, Cleft-Containing, Polyphenyl Polycyclic Aromatic Hydrocarbons" @default.
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- W2952332006 doi "https://doi.org/10.1021/ja971261k" @default.
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