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- W2952345650 abstract "General methods for the analysis of step-current measurements on intercalation devices are applied to an aqueous, protonic, tungsten oxide-based device. Plots of the built-in potential as a function of the passed charge, V{sub bi}({Delta}Q), are generated. Methods are demonstrated for extracting a useful indicator of the intercalation level from {Delta}Q and for relating V{sub bi} to the applied potential. An intercalation efficiency, {zeta}, is defined, and {zeta}(V{sub bi}) plots are generated. With proper accounting for extraneous contributions, {zeta}(V{sub bi}) provides a measure of the effective site energy distribution and of the instantaneous efficiency (or capacity) of the intercalation process. A nonfaradaic spontaneous deintercalation process has been observed which acts to deintercalate the film without contributing to the measured current. Methods for including this effect in the analysis are presented in terms of a virtual current." @default.
- W2952345650 created "2019-06-27" @default.
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- W2952345650 date "2010-08-04" @default.
- W2952345650 modified "2023-09-26" @default.
- W2952345650 title "ChemInform Abstract: Step-Current Analysis of the Built-in Potential of Tungsten Oxide- Based Electrochromic Devices and the Effects of Spontaneous Hydrogen Deintercalation." @default.
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- W2952345650 doi "https://doi.org/10.1002/chin.199726021" @default.
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