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- W2952345937 abstract "This article discusses polynuclear metal complexes of Schiff base macrocycles and their potential application to the modelling of metallobiosites, in particular di- and tri-nuclear copper(II)-containing sites. A brief perspective of the area is presented and then the article addresses the development of pyridinyl-derived bibracchial (doubly pendant-armed) Schiff base macrocycles and their metal complexes. The cleft-like configurations of the complexes bear resemblance to the metal-containing pockets present in metalloproteins. A ‘first generation’ model for the trinuclear copper site in ascorbate oxidase, and a dinuclear manganese(II) complex bearing a single acetato-bridge, and which may have relevance to the modelling of dinuclear manganese biosites, are discussed. An extension of the work to thiophene-derived macrocycles and their dicopper(I) complexes is also presented." @default.
- W2952345937 created "2019-06-27" @default.
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- W2952345937 date "1996-02-01" @default.
- W2952345937 modified "2023-10-11" @default.
- W2952345937 title "Metal complexes of bibracchial Schiff base macrocycles" @default.
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- W2952345937 doi "https://doi.org/10.1016/0010-8545(95)01156-0" @default.
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