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- W2952349969 abstract "Abstract Six‐membered cyclic nitronates couple with amines or their N ‐silyl derivatives in a diastereoselective fashion to give 3‐amino‐substituted nitroso acetals in 53–89 % yield through silyl triflate electrophilic catalysis. Stereodifferentiation of this process is determined by thermodynamic control, which is realized due to reversibility of amine addition and a decreased nitrogen inversion barrier in the resulting nitroso acetals. Selected chemical transformations of nitroso acetals were examined." @default.
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- W2952349969 date "2013-07-16" @default.
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- W2952349969 title "Stereoselective Amine Addition to Six-Membered Cyclic Nitronates Promoted by Silyl Triflate" @default.
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- W2952349969 doi "https://doi.org/10.1002/ejoc.201300511" @default.
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