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- W2952352692 abstract "The reaction of 3,4-bis(O-tert-butyldimethylsilyl)-6-O-tosyl-D-glucal 4 with the Koser reagent [PhI(OH)OTs] unexpectedly afforded tetrahydrofurfural 6 as well as 2,3-anhydropyranose 7 as major products. This unprecedented, stereoselective transformation helps to gain further insight into the mechanism of the well-documented hypervalent iodine-promoted allylic oxidation of cyclic enol ethers. A novel chemoenzymatic method for the preparation of glucal 4 in high yield is presented." @default.
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- W2952352692 date "1995-11-01" @default.
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- W2952352692 title "3,4-bis(O-tert-butyldimethylsilyl)-6-O-tosyl-D-glucal: A probe for the mechanism of the iodine(III)-promoted allylic oxidation of glycals" @default.
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- W2952352692 doi "https://doi.org/10.1002/jlac.1995199511289" @default.
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