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- W2952354472 abstract "The isomeric compounds 1 and 3, which differ only in the position of a methyl substituent, give opposite chemoselectivities in an esterase-catalyzed hydrolysis reaction. The esterase was chemoselective for the oxoester in 1, but for the thiol ester group in 3. A high enantioselectivity was observed for both 1 and 3." @default.
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- W2952354472 date "1999-06-04" @default.
- W2952354472 modified "2023-10-02" @default.
- W2952354472 title "Effect of the α-Methyl Substituent on Chemoselectivity in Esterase-Catalyzed Hydrolysis of <i>S</i>-Acetyl Sulfanylalkanoates" @default.
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- W2952354472 doi "https://doi.org/10.1021/ol990544+" @default.
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