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- W2952355498 abstract "Alkene hydrosilylation is typically performed with Pt catalysts, but inexpensive base-metal catalysts would be preferred. We report a Co catalyst for anti-Markovnikov alkene hydrosilylation that can be used without added solvent at low temperatures with low loadings, and can be generated in situ from an air-stable precursor that is simple to synthesize from low-cost, commercially available materials. In addition, a mixture of Co catalysts performs a tandem catalytic alkene isomerization/hydrosilylation reaction that converts multiple isomers of hexene to the same terminal product. This regioconvergent reaction uses isomerization as a benefit rather than a hindrance." @default.
- W2952355498 created "2019-06-27" @default.
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- W2952355498 date "2016-03-01" @default.
- W2952355498 modified "2023-09-27" @default.
- W2952355498 title "ChemInform Abstract: Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst." @default.
- W2952355498 cites W2290027198 @default.
- W2952355498 doi "https://doi.org/10.1002/chin.201613051" @default.
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