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• W2952372131 abstract "An enantioselective total synthesis of AI-77-B (1), a gastroprotective substance isolated from a culture broth of Bacillus pumilus AI-77, was performed in high overall yield. In this synthesis, the dihydroisocoumarin part 14 and the dihydroxyamino acid part 20 were both assembled from d-ribose as the common chiral source. For the construction of 14 a bromobenzofuran derivative was used as a novel salicylic acid synthon. Finally, DEPC-mediated condensation of 14 and 20 yielded AI-77-B (1)." @default.
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• W2952372131 date "1999-06-25" @default.
• W2952372131 modified "2023-10-02" @default.
• W2952372131 title "A New Enantioselective Total Synthesis of AI-77-B" @default.
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• W2952372131 doi "https://doi.org/10.1021/ol990102y" @default.
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