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- W2952390817 abstract "Irradiation of benzophenone O-acetyloxime, O-phenylacetyloxime, O-benzoyloxime, and O-(p-chlorobenzoyl)oxime in benzene, toluene, chlorobenzene, or o-xylene effected aromatic substitution on the solvent molecules by diphenylmethaniminyl radicals to give N-diphenylmethylenearylamines only when benzoxyl or p-chlorobenzoxyl radicals were generated concurrently. A mechanism involving a participation of the sufficiently long-lived acyloxyl radicals is proposed for the iminylation reaction on the basis of the reactivity patterns in this substitution reaction. o-Phenylbenzophenone O-benzoyloxime was also photolyzed in benzene to give 9-phenylphenanthridine, the intramolecular cyclization product of 2-biphenylylphenylmethaniminyl radicals." @default.
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- W2952390817 date "1976-10-19" @default.
- W2952390817 modified "2023-09-25" @default.
- W2952390817 title "ChemInform Abstract: HOMOLYTIC AROMATIC SUBSTITUTION BY IMINYL RADICALS. PHOTOLYSIS OF AROMATIC KETONE O-ACYLOXIMES IN AROMATIC SOLVENTS" @default.
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- W2952390817 doi "https://doi.org/10.1002/chin.197642123" @default.
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