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- W2952393420 abstract "Thermolysis of the aziridine ester, obtained from (S)-O-benzylglycidol, afforded the pyrrolidine lactone bearing a quaternary carbon center stereo-specifically in a good yield via intramolecular cycloaddition of the 1,3-dipole. The adduct (11) could be converted into natural (−)-mesembrine, the major alkaloid of Sceletium namaquense, and its N-demethyl derivative via a 8 step sequence of reactions." @default.
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- W2952393420 date "1990-07-01" @default.
- W2952393420 modified "2023-10-14" @default.
- W2952393420 title "Enantiospecific Construction of Quaternary Carbon Center via Intramolecular 1,3-Dipolar Cycloaddition. A New Route to Natural (−)-Mesembrine from (<i>S</i>)-<i>O</i>-Benzylglycidol" @default.
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- W2952393420 doi "https://doi.org/10.1246/cl.1990.1239" @default.
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