Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952395206> ?p ?o ?g. }
- W2952395206 abstract "Publisher Summary This chapter concentrates on the theoretical studies carried out for systems with acyloxy or phosphatoxy substituents, together with the relevant experimental results. Particular attention has been paid to quantitative aspects of the charge distribution in ground and transition states. Concerted rearrangement or stepwise heterolytic dissociation/recombination depends on the character of the migrating group, the substitution pattern, and the solvent polarity. It may also depend on the presence of a catalyst present in the reaction medium. There is not a single general mechanism for the 1, 2-migration reaction in β-substituted alkyl radicals that may easily be illustrated with sdq- and dsdq-plots of four selected systems. This selection includes transition states from chlorine, acyloxy, and phosphatoxy migration reactions as well as three-and five-membered ring transition states in order to illustrate, how broadly the charge density/spin density space is covered in 1, 2- migration reactions." @default.
- W2952395206 created "2019-06-27" @default.
- W2952395206 creator A5055634298 @default.
- W2952395206 date "2003-01-01" @default.
- W2952395206 modified "2023-09-25" @default.
- W2952395206 title "Charge distribution and charge separation in radical rearrangement reactions" @default.
- W2952395206 cites W1674235549 @default.
- W2952395206 cites W1909422527 @default.
- W2952395206 cites W1964610733 @default.
- W2952395206 cites W1966250107 @default.
- W2952395206 cites W1968128440 @default.
- W2952395206 cites W1969542395 @default.
- W2952395206 cites W1970094723 @default.
- W2952395206 cites W1972755427 @default.
- W2952395206 cites W1976329342 @default.
- W2952395206 cites W1976563484 @default.
- W2952395206 cites W1979091434 @default.
- W2952395206 cites W1980885691 @default.
- W2952395206 cites W1983570806 @default.
- W2952395206 cites W1985041965 @default.
- W2952395206 cites W1988009946 @default.
- W2952395206 cites W1988055233 @default.
- W2952395206 cites W1990417626 @default.
- W2952395206 cites W1992145745 @default.
- W2952395206 cites W1992272627 @default.
- W2952395206 cites W1994962919 @default.
- W2952395206 cites W1997823913 @default.
- W2952395206 cites W1998413629 @default.
- W2952395206 cites W1999838201 @default.
- W2952395206 cites W2001401168 @default.
- W2952395206 cites W2003064706 @default.
- W2952395206 cites W2004177598 @default.
- W2952395206 cites W2004477694 @default.
- W2952395206 cites W2010092973 @default.
- W2952395206 cites W2012522257 @default.
- W2952395206 cites W2013305473 @default.
- W2952395206 cites W2017626786 @default.
- W2952395206 cites W2019104683 @default.
- W2952395206 cites W2021202167 @default.
- W2952395206 cites W2021502908 @default.
- W2952395206 cites W2021811173 @default.
- W2952395206 cites W2023507667 @default.
- W2952395206 cites W2026522321 @default.
- W2952395206 cites W2027784487 @default.
- W2952395206 cites W2029413799 @default.
- W2952395206 cites W2029998391 @default.
- W2952395206 cites W2032577464 @default.
- W2952395206 cites W2036690044 @default.
- W2952395206 cites W2036982311 @default.
- W2952395206 cites W2038767330 @default.
- W2952395206 cites W2049897435 @default.
- W2952395206 cites W2054555560 @default.
- W2952395206 cites W2055143357 @default.
- W2952395206 cites W2055779373 @default.
- W2952395206 cites W2056471532 @default.
- W2952395206 cites W2058247012 @default.
- W2952395206 cites W2058848030 @default.
- W2952395206 cites W2059831734 @default.
- W2952395206 cites W2062628138 @default.
- W2952395206 cites W2063907472 @default.
- W2952395206 cites W2064466074 @default.
- W2952395206 cites W2069039374 @default.
- W2952395206 cites W2069943490 @default.
- W2952395206 cites W2078826595 @default.
- W2952395206 cites W2082808178 @default.
- W2952395206 cites W2083295410 @default.
- W2952395206 cites W2083715111 @default.
- W2952395206 cites W2084686897 @default.
- W2952395206 cites W2086365356 @default.
- W2952395206 cites W208767372 @default.
- W2952395206 cites W2091771219 @default.
- W2952395206 cites W2092385767 @default.
- W2952395206 cites W2092446590 @default.
- W2952395206 cites W2104432062 @default.
- W2952395206 cites W2114463368 @default.
- W2952395206 cites W2137385438 @default.
- W2952395206 cites W2142889117 @default.
- W2952395206 cites W2949798950 @default.
- W2952395206 cites W2950145870 @default.
- W2952395206 cites W2951455451 @default.
- W2952395206 cites W2951629063 @default.
- W2952395206 cites W2951655311 @default.
- W2952395206 cites W2951754442 @default.
- W2952395206 cites W2951996052 @default.
- W2952395206 cites W2952210728 @default.
- W2952395206 cites W2952287586 @default.
- W2952395206 cites W2953233311 @default.
- W2952395206 cites W2953379174 @default.
- W2952395206 cites W583523183 @default.
- W2952395206 doi "https://doi.org/10.1016/s0065-3160(03)38003-7" @default.
- W2952395206 hasPublicationYear "2003" @default.
- W2952395206 type Work @default.
- W2952395206 sameAs 2952395206 @default.
- W2952395206 citedByCount "2" @default.
- W2952395206 crossrefType "book-chapter" @default.
- W2952395206 hasAuthorship W2952395206A5055634298 @default.
- W2952395206 hasConcept C102931765 @default.
- W2952395206 hasConcept C121332964 @default.
- W2952395206 hasConcept C139066938 @default.
- W2952395206 hasConcept C147597530 @default.