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- W2952414307 abstract "Complementary to the Claisen rearrangement, the title reaction—which when carried out with chelated enolates of amino acid esters as nucleophiles gives rise to unsaturated amino acids—preferentially provides anti instead of syn products. This palladium-catalyzed reaction proceeds under very mild conditions and is suitable for the synthesis of enantiomerically pure amino acids (see reaction scheme). Tfa=trifluoroacetyl." @default.
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- W2952414307 date "1999-05-17" @default.
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- W2952414307 title "Chelated Enolates of Amino Acid Esters—Efficient Nucleophiles in Palladium-Catalyzed Allylic Substitutions" @default.
- W2952414307 doi "https://doi.org/10.1002/(sici)1521-3773(19990517)38:10<1468::aid-anie1468>3.0.co;2-o" @default.
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