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• W2952416060 abstract "Abstract Sulfanyl radicals trigger a tandem addition–cyclization protocol in linalool or citronelene derivatives for the efficient construction of the iridane monoterpene skeleton. Best results in yields and diastereoselectivity were obtained when phenylethylsulfanyl was used as radical initiator. We have proved the utility of this protocol with the enantiospecific synthesis of natural iridane dehydroiridomyrmecin starting from a (−)-linalyl acetate ester derivative in five steps with a 28% overall yield." @default.
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• W2952416060 date "2008-05-01" @default.
• W2952416060 modified "2023-09-26" @default.
• W2952416060 title "Tandem addition–cyclization mediated by sulfanyl radicals: a versatile strategy for iridoids synthesis" @default.
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• W2952416060 doi "https://doi.org/10.1016/j.tet.2008.03.058" @default.
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