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- W2952431919 abstract "When acetonitrile solutions of tetrathiafulvalene [i.e., (C3S2H2)2; herein called TTF] and iodine, I2, are allowed to mix by diffusion, monoclinic crystals are formed with the approximate composition (TTF)7I5. These crystals have an electrical conductivity along the needle axis c of 300 ohm−1⋅cm−1 at room temperature. A complete crystal structure analysis based on an approximate supercell with a=48.016(16) A, b= 16.041(6) A, c=24.877(7) A, β=91.31(2) °, Z=12 (RRF)7I5 was carried out using space group P21/a with 225 nonhydrogen atoms in the asymmetric unit. The TTF molecules stack along c and form a TTF subcell a1=a/3, b1=b, c1=c/7, Z1=4 TTF and subcell symmetry C2/m. The iodine atoms are in chains along c and form an A‐centered sublattice complex (space group A2/m) with a2=8.213 A, b2= b, c2=5.023 A, β2=103.0°, and Z2=2 I. The supercell space group P21/a is the mathematical intersection of the two subcell space groups. The supercell is only approximate because 5c2=25.113(14) A which is about 1% longer tha..." @default.
- W2952431919 created "2019-06-27" @default.
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- W2952431919 date "1976-06-22" @default.
- W2952431919 modified "2023-09-26" @default.
- W2952431919 title "ChemInform Abstract: SUPERSTRUCTURE AND MODULATION WAVE ANALYSIS FOR THE UNIDIMENSIONAL CONDUCTOR HEPTA- (TETRATHIAFULVALENE) PENTAIODIDE" @default.
- W2952431919 cites W1983720770 @default.
- W2952431919 doi "https://doi.org/10.1002/chin.197625073" @default.
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