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- W2952442068 abstract "The Ireland-Claisen rearrangement of a variety of O-protected 2-butenyl glycolates via chelated boron and tin triflates to give after esterification methyl 2-methoxy/benzyloxy-3-methyl-4-pentenoates is described. Diastereoselectivities as high as 99.5% were observed. The rates of rearrangement involving boron enolates are higher than those involving silyl ketene acetals or lithium enolates." @default.
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- W2952442068 date "1992-01-01" @default.
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- W2952442068 title "Acyclic Diastereoselection via Claisen Rearrangement with Boron Enolates. Chelation Control of Enolate Geometry" @default.
- W2952442068 doi "https://doi.org/10.1055/s-1992-21274" @default.
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