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- W2952451301 abstract "An enantioselective alkoxylation/Claisen rearrangement reaction was achieved by a strategic desymmetrization of 1,4-dienes under the catalysis of (S)-DTBM-Segphos(AuCl)2/AgBF4. This reaction system was highly selective for the formation of 3,3-rearrangement products, providing cycloheptenes with various substitutions in good yield and good to excellent enantioselectivity. This transformation was further extended to bicyclic ring substrates, providing the opportunity to easily assemble 5,6- and 6,7-fused ring systems." @default.
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- W2952451301 date "2015-10-27" @default.
- W2952451301 modified "2023-09-27" @default.
- W2952451301 title "ChemInform Abstract: Gold(I)-Catalyzed Desymmetrization of 1,4-Dienes by an Enantioselective Tandem Alkoxylation/Claisen Rearrangement." @default.
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- W2952451301 doi "https://doi.org/10.1002/chin.201546091" @default.
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