Matches in SemOpenAlex for { <https://semopenalex.org/work/W2952463698> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2952463698 abstract "The asymmetric Povarov reaction with α-alkyl styrenes as dienophiles was catalyzed by an N,N′-dioxide L4–Sc(OTf)3 complex. Enantiopure tetrahydroquinoline derivatives with a quaternary stereocenter at the C4 position were synthesized for the first time. A wide variety of α-alkyl styrenes and N-aryl aldimines were tolerated in the reaction, to give excellent diastereo- (up to 99:1 d.r.) and enantioselectivities (92 to >99 % ee). In addition, the reaction could be performed on the gram scale without any loss of yield, diastereoselectivity, or enantioselectivity. An intermolecular hydrogen-shift reaction was found to be a side reaction, which offered a method to synthesize the corresponding quinoline derivatives with chiral quaternary sterocenters." @default.
- W2952463698 created "2019-06-27" @default.
- W2952463698 creator A5032926098 @default.
- W2952463698 creator A5054000373 @default.
- W2952463698 creator A5072536000 @default.
- W2952463698 creator A5077217676 @default.
- W2952463698 creator A5077232855 @default.
- W2952463698 creator A5081137661 @default.
- W2952463698 creator A5091228324 @default.
- W2952463698 date "2012-04-12" @default.
- W2952463698 modified "2023-09-23" @default.
- W2952463698 title "ChemInform Abstract: Asymmetric Synthesis of Tetrahydroquinolines with Quaternary Stereocenters Through the Povarov Reaction." @default.
- W2952463698 cites W2144417580 @default.
- W2952463698 doi "https://doi.org/10.1002/chin.201219151" @default.
- W2952463698 hasPublicationYear "2012" @default.
- W2952463698 type Work @default.
- W2952463698 sameAs 2952463698 @default.
- W2952463698 citedByCount "0" @default.
- W2952463698 crossrefType "journal-article" @default.
- W2952463698 hasAuthorship W2952463698A5032926098 @default.
- W2952463698 hasAuthorship W2952463698A5054000373 @default.
- W2952463698 hasAuthorship W2952463698A5072536000 @default.
- W2952463698 hasAuthorship W2952463698A5077217676 @default.
- W2952463698 hasAuthorship W2952463698A5077232855 @default.
- W2952463698 hasAuthorship W2952463698A5081137661 @default.
- W2952463698 hasAuthorship W2952463698A5091228324 @default.
- W2952463698 hasConcept C134121241 @default.
- W2952463698 hasConcept C134195300 @default.
- W2952463698 hasConcept C146686406 @default.
- W2952463698 hasConcept C155647269 @default.
- W2952463698 hasConcept C161790260 @default.
- W2952463698 hasConcept C178790620 @default.
- W2952463698 hasConcept C185592680 @default.
- W2952463698 hasConcept C191897082 @default.
- W2952463698 hasConcept C192562407 @default.
- W2952463698 hasConcept C21951064 @default.
- W2952463698 hasConcept C2776309666 @default.
- W2952463698 hasConcept C2780263894 @default.
- W2952463698 hasConcept C2781076698 @default.
- W2952463698 hasConcept C2991944050 @default.
- W2952463698 hasConcept C67524406 @default.
- W2952463698 hasConcept C93237805 @default.
- W2952463698 hasConceptScore W2952463698C134121241 @default.
- W2952463698 hasConceptScore W2952463698C134195300 @default.
- W2952463698 hasConceptScore W2952463698C146686406 @default.
- W2952463698 hasConceptScore W2952463698C155647269 @default.
- W2952463698 hasConceptScore W2952463698C161790260 @default.
- W2952463698 hasConceptScore W2952463698C178790620 @default.
- W2952463698 hasConceptScore W2952463698C185592680 @default.
- W2952463698 hasConceptScore W2952463698C191897082 @default.
- W2952463698 hasConceptScore W2952463698C192562407 @default.
- W2952463698 hasConceptScore W2952463698C21951064 @default.
- W2952463698 hasConceptScore W2952463698C2776309666 @default.
- W2952463698 hasConceptScore W2952463698C2780263894 @default.
- W2952463698 hasConceptScore W2952463698C2781076698 @default.
- W2952463698 hasConceptScore W2952463698C2991944050 @default.
- W2952463698 hasConceptScore W2952463698C67524406 @default.
- W2952463698 hasConceptScore W2952463698C93237805 @default.
- W2952463698 hasLocation W29524636981 @default.
- W2952463698 hasOpenAccess W2952463698 @default.
- W2952463698 hasPrimaryLocation W29524636981 @default.
- W2952463698 hasRelatedWork W1987393521 @default.
- W2952463698 hasRelatedWork W2003576405 @default.
- W2952463698 hasRelatedWork W2015525681 @default.
- W2952463698 hasRelatedWork W2018914541 @default.
- W2952463698 hasRelatedWork W2057023171 @default.
- W2952463698 hasRelatedWork W2070921346 @default.
- W2952463698 hasRelatedWork W2126843749 @default.
- W2952463698 hasRelatedWork W2132477542 @default.
- W2952463698 hasRelatedWork W2141357815 @default.
- W2952463698 hasRelatedWork W2144417580 @default.
- W2952463698 hasRelatedWork W2330156137 @default.
- W2952463698 hasRelatedWork W2508436469 @default.
- W2952463698 hasRelatedWork W2949470462 @default.
- W2952463698 hasRelatedWork W2949825067 @default.
- W2952463698 hasRelatedWork W2950302785 @default.
- W2952463698 hasRelatedWork W2950472427 @default.
- W2952463698 hasRelatedWork W2950667600 @default.
- W2952463698 hasRelatedWork W2951964617 @default.
- W2952463698 hasRelatedWork W2952217811 @default.
- W2952463698 hasRelatedWork W2952861861 @default.
- W2952463698 isParatext "false" @default.
- W2952463698 isRetracted "false" @default.
- W2952463698 magId "2952463698" @default.
- W2952463698 workType "article" @default.